First, make the substitutions
$$
x=
\frac{a}{b+c},
\quad
y=
\frac{b}{a+c},
\quad
z=
\frac{c}{a+b}.
$$
The strategy will be to reduce the problem to an inequality in the single variable $t=(xyz)^{1/3}$. Note that $xy+yz+xz+2xyz=1$, and the inequality to be proved is
$$
\frac{16}{27}\left(x+y+z\right)^3+(xyz)^{1/3}\geq\frac{5}{2}.
$$
Now
$$
\frac{(x+y+z)^2}{3}\geq xy+yz+xz=1-2xyz
$$
and also $x+y+z\geq3/2$ by Nesbitt's inequality. Therefore,
$$
\frac{16}{27}(x+y+z)^3=\frac{16}{9}\cdot(x+y+z)\cdot\frac{(x+y+z)^2}{3}\geq\frac{8}{3}(1-2xyz),
$$
and it is sufficient to prove the inequality
$$
\frac{8}{3}(1-2xyz)+(xyz)^{1/3}\geq\frac{5}{2}.
$$
Now $xyz\leq1/8$, because AM-GM gives
$8abc\leq (a+b)(b+c)(a+c)$ by grouping pairs on the right-hand side (e.g., $2abc\leq a^2b+bc^2$). Thus by setting $t=(xyz)^{1/3}$, we are reduced to proving that the polynomial
$$
f(t):=
8\left(\frac{1-2t^3}{3}\right)+t-\frac{5}{2}
=
\frac{1}{6}+t-\frac{16}{3}t^3.
$$
is nonnegative for $t\in[0,1/2]$. Since $f(0)>0$ and $f(1/2)=0$, we can show that $f(c)>0$ whenever $c$ is a critical point of $f$. But $f'(t)=1-16t^2$, which has $c=1/4$ as its only zero in $[0,1/2]$. As $f(1/4)=4/12>0$, we are done.