The statement trivially holds if $\phi = 0$. For the purposes of the proofs below, we assume this is not the case.
Hint: (if you know about quotient spaces): consider the induced maps $\tilde \phi : V/\ker \phi \to \Bbb F$ and $\tilde \sigma : V / \ker \phi \to \Bbb F$. Note that $\tilde \sigma = \alpha \tilde \phi$, and conclude that $\sigma = \alpha \phi$.
Hint: (alternate approach): consider the linear map $T:V \to \Bbb F^2$ given by $T(v) = (\phi(v),\sigma(v))$. If $\phi(v) = 0 \implies \sigma(v) = 0$, then $T$ fails to be onto. Thus, there exists a non-zero map $f: \Bbb F^2 \to \Bbb F$ (given by $f(x_1,x_1) = a_1x_1 + a_2x_2$) such that $f$ is zero over the image of $T$. Use $a_1,a_2$ to reach the desired conclusion.