There is some information missing, especially what the domain of your operator is, in other words: What functions are you allowed to use for $f(x)$?
This could in theory be an function $f: \mathbb R \rightarrow \mathbb R$, like $f(x)=\sin(x)$, but from your "known answer" it seems to be that $f(x)$ is restricted to polynomials, so I'll assume that.
$T(1)$ is simply the function that $T$ produces when you put in the constant function $f(x)=1$ for all $x \in \mathbb R$. We have in that case $f'(x)=0$ for all $x \in \mathbb R$ and $f(2)=f(3)=1$ and the formula
$$T(f(x))=xf'(x)+f(2)x+f(3)$$ results in
$$ T(1) =x\cdot 0 + 1\cdot x + 1 = x+1.$$
If you use $f(x)=x$ for all $x \in \mathbb R$, you get $f'(x)=1$ for all $x \in \mathbb R$ and $f(2)=2, f(3)=3$ and hence
$$T(x)=x\cdot 1 + 2\cdot x + 3 = 3x+3.$$
You should be able to verify $T(x^2)$ on your own now, and maybe find the general formula for $T(x^n)$.