I thought it might be instructive to present a way forward the relies on only the series expansion of the exponential function, evaluating two integrals using reduction formulae, and straightforward arithmetic. To that end, we proceed.
Using the Taylor series for $e^t=\sum_{n=0}^\infty \frac{t^n}{n!}$, with $t=2x\cos(\theta)$, we can write $I_0(2x)$ as
$$\begin{align}
I_0(2x)&=\frac1\pi \int_0^\pi e^{2x\cos(\theta)}\,d\theta\\\\
&=\frac1\pi \sum_{n=0}^\infty \frac{(2x)^n}{n!}\int_0^\pi \cos^n(\theta)\,d\theta\tag 1
\end{align}$$
Next, using the reduction formula for $\int_0^\pi \cos^n(\theta)\,d\theta=\frac{n-1}{n}\int_0^\pi \cos^{n-2}(\theta)\,d\theta$ reveals
$$\int_0^\pi \cos^n(\theta)\,d\theta=\begin{cases}\pi\frac{n!}{(n!!)^2}&,n\,\text{even}\\\\0&,n\,\text{odd}\tag2\end{cases}$$
Using $(1)$ and $(2)$, we find that
$$\begin{align}
\int_0^\infty xe^{-x^2}I_0(2x)\,dx&= \frac1\pi\sum_{n=0}^\infty \underbrace{\frac{4^n}{(2n)!}\left(\pi\,\frac{(2n)!}{((2n)!!)^2}\right)}_{=\frac{\pi}{(n!)^2}}\,\,\underbrace{\int_0^\infty x^{2n+1}e^{-x^2}\,dx}_{=\frac12 n!}\\\\
&=\frac12\sum_{n=0}^\infty \frac{1}{n!}\\\\
&=\frac{e}{2}
\end{align}$$
where we used the reduction formula $\int_0^\infty x^{2n+1}e^{-x^2}\,dx=n\int_0^\infty x^{2n-1}e^{-x^2}\,dx$, along with the elementary integral $\int_0^\infty xe^{-x^2}\,dx=\frac12$, to establish $\int_0^\infty x^{2n+1}e^{-x^2}\,dx=\frac12 n!$.
Tools Used: The Taylor Series for $e^x$, the reduction formula for $\int_0^\pi \cos^n(x)\,dx$, and the reduction formula for $\int_0^\infty x^{2n+1}e^{-x^2}\,dx$