Let $\Delta ABC$ be our triangle, where $AB=BC$ and $\measuredangle ABC=2x$.
Hence, $P_{\Delta ABC}=2r\left(\cot{x}+2\tan\left(\frac{\pi}{4}+\frac{x}{2}\right)\right)$ and we need to prove that $\min\limits_{\left(0,\frac{\pi}{2}\right)}f=3\sqrt3$, where
$$f(x)=\cot{x}+2\tan\left(\frac{\pi}{4}+\frac{x}{2}\right).$$
Indeed,
$$f'(x)=\frac{1}{\cos^2\left(\frac{\pi}{4}+\frac{x}{2}\right)}-\frac{1}{\sin^2x}=\frac{\left(\sin{x}-\cos\left(\frac{\pi}{4}+\frac{x}{2}\right)\right)\left(\sin{x}+\cos\left(\frac{\pi}{4}+\frac{x}{2}\right)\right)}{\cos^2\left(\frac{\pi}{4}+\frac{x}{2}\right)\sin^2x}.$$
Since $\sin{x}+\cos\left(\frac{\pi}{4}+\frac{x}{2}\right)>0$ for $0
we see that $f'(x)=0$ on $\left(0,\frac{\pi}{2}\right)$ for $x=\frac{\pi}{6}$ only
and since $f'(x)<0$ on $\left(0,\frac{\pi}{6}\right)$ and $f'(x)>0$ on $\left(\frac{\pi}{6},\frac{\pi}{2}\right)$,
we see that $f$ gets on $\left(0,\frac{\pi}{2}\right)$ a minimal value for $x=\frac{\pi}{6}$.
Since $f\left(\frac{\pi}{6}\right)=3\sqrt3$, we are done!