The question of whether the equation $$x^2 \equiv 3 \pmod{7}$$ has any solutions is equivalent to the question is $$x^{2} = 3$$ solvable for $x \in \mathbb{Z}/ 7\mathbb{Z}$.
So, as Donald Splutterwit mentions in the comments, we can calculate
the value of $x^{2}$ for each $x \in \mathbb{Z}/ 7\mathbb{Z}$ and check whether it is equal to $3$.
In general, the question of whether for $p$ prime and fixed integer $n$ the equation, $$x^{2} \equiv n \pmod{p}$$ has a solution is answered by Gauss's quadratic reciprocity.
$\textbf{Edit:}$
To expand upon the answer, suppose that there exists $x\in \mathbb{Z}$ such that $$x^{2} \equiv 3 \pmod{7},$$ then $7 \mid (x^{2} - 3)$, which implies that there is an $a\in \mathbb{Z}$ so that
$$x^{2} - 3 = 7a.$$
Then, by the Euclidean division algorithm, $x = 7k+r$ for some $0 \leq r \leq 6$. Substituting this expression into the above formula yields
$$49x^{2} + 14kr + r^{2} - 3 = 7a,$$ which is equivalent to saying that there is $a^{'} \in \mathbb{Z}$ so that
$$r^{2} - 3 = 7a^{'}.$$ (Just bring the terms on the LHS divisible by $7$ to the RHS and factor out a $7$.)
Now, we see that if $7 \mid (x^{2} - 3)$, then $7 \mid (r^{2} - 3)$ for some $0 \leq r \leq 6$.
So, to show that $7 \nmid (x^{2} - 3)$ for all $x\in \mathbb{Z}$, it is enough to show that $7 \nmid (r^{2} - 3)$ for $r \in \{0,1,\ldots, 6\}.$