Properties are just anything about an object of which you can say that it is right or wrong. For example, "it is red" is a property that can apply e.g. top an apple: The apple may or may not be red.
Relations are properties that involve two or more objects. For example, "this apple is larger than that one over there." Here"is larger than" is the relation, applied to the objects "this apple" and "that one over there". It is clear that either this apple is larger than that one over there, or it is not.
So for a relation you have several sets of things your relation is meant to describe (which might be the same, as in the case of the apples above, or it may be different, e.g. for the relation "[software] runs on [hardware]", one set is the set of all software, and the other set is the set of all hardware).
A relation can be completely specified by specifying every tuple of objects for which the relation is true. For example, the ternary relation "[application] tuns under [operating system] on [hardware]" can be specified by a list of the form "Word runs under Windows on PCs, Word runs under OS X on Macs, bash runs under Linux on PCs, bash runs under FreeBSD on PCs, bash runs under Linux on Raspberry Pi, …), or in short, {(Word,Windows,PC),(Word, OS X, Mac), (bash,Linux,PC), (bash,FreeBSD,PC), (bash,Linux,Raspberry Pi), …}.
Of course in mathematics we are usually not interested in apples of software comaptibility, but in relations of mathematical objects. For example, given the set of natural numbers, you are interested in the relation "is the same number" (in short, "equals"), given by the set $\{(0,0),(1,1),(2,2),\ldots\}$. Or you might be interested in the relation "is smaller than", given by the set $\{(0,1),(0,2),(1,2),(0,3),(1,3),(2,3),(0,4),\ldots\}$. Or in the ternary relation "the sum of [number] and [number] is [number]", given by the set $\{(0,0,0),(1,0,1),(0,1,1),(2,0,2),(1,1,2),(0,2,2),\ldots\}$.