No, even the marginal distributions are not the same. Consider for simplicity $n=2$. Method 1 generates values $a_1$, $1-a_1$ both Uniformly distributed in $(0,\,1)$.
For Method 2, let us find the distribution of $\frac{X}{X+Y}$, where $X$ and $Y$ are independent r.v.'s Uniformly distributed in $(0,\,1)$. It makes no sense to take the uniform distribution on the interval $(0,\,n)$ as the length of the segment here is the scaling parameter only, and the ratio does not depend on it.
$$
P\left(\dfrac{X}{X+Y}
One can calculate this probability separately for $0
These functions are very different from Uniform CDF's in Method 1.
For Method 1 one can write joint distribution. In 2nd volume of W.Feller An Introduction to Probability Theory and Its Applications one can find result of B.De Finetti, 1964. See exercise 23 to 1st Chapter.
For $x_1\geq 0$, ..., $x_n\geq 0$
$$
P(a_1>x_1, a_2-a_1>x_2, \ldots, 1-a_{n-1}>x_n)=(1-x_1-\ldots-x_n)^{n-1}_+
$$
where $(x)_+=\max(x,0)$. Here $a_1\leq a_2\leq\ldots \leq a_{n-1}$ are order statistics for independent Uniform random numbers.
I do not know how joint distribution looks like for Method 2. Doubt that it looks simple.
If we take for Method 2 independent r.v. $X_1,\ldots,X_n$ from the same Exponential distribution, we obtain the same joint distribution of $X_i/(X_1+\ldots+X_n)$, $i=1,\ldots,n$ as in Method 1.
This result is discussed in the 2nd Vol. of W.Feller's book, in paragraph 3 Chapter III.