Since you didn't mention how the required operations (addition and scalar multiplication) are defined on $W$, I assume you mean they are the standard operations. You also need to specify what your set of scalars is.
For $W$ to be a subspace of $V$, the Subspace Theorem requires (1) the existence of a zero vector in $W$, (2) $W$ is closed under addition, and (3) $W$ is closed under scalar multiplication.
Any of these is easy to violate. The zero vector would be the $3\times 3$ matrix of zeros, which is not invertible, so it does not live in $W$ and thus (1) fails.
You could also show (2) fails by considering the $3\times 3$ identity matrix, $I$. $I\in W$ and $-I\in W$ but $I+(-I)=0$ (the zero matrix) and thus is not invertible, so it cannot be in $W$. Thus, (2) fails.
You could show (3) fails by just picking any matrix $M\in W$ and multiplying it by the zero scalar to obtain the zero matrix, which we've established is not in $W$. Thus, (3) fails.