Question
Is there a (preferably natural combinatorial) theorem in ACA that cannot be proven in $Π^1_1$-CA$_0$?
Motivation
On reading many introductory materials on reverse mathematics, there seems to be a focus on subsystems of arithmetic that do not have the full induction schema. In particular there are two systems ACA$_0$ and $Π^1_1$-CA$_0$, the former being predicative while the latter being impredicative. By predicative I mean that one is only allowed to construct collections that quantify over previously constructed collections.
However, in my mind the motivation for ACA$_0$ is that we already assume the existence of natural numbers, and that membership of a natural number in an arithmetical set has a definite answer, even if we cannot figure out the answer. (The justification for the latter could be via using game semantics to interpret quantified statements, and then arguing that finite games are determined, but that is not the point of my question.) Since we assume the natural numbers as some fixed and complete collection, which is somewhat necessary to justify that arithmetical sets are well-defined, we also would not be wrong in adding full induction in the form of the second-order axiom schema "$P(0) \land \forall n\ ( P(n) \to P(n+1) ) \to \forall n\ ( P(n) )$" for every predicate $P$ (which can have second-order quantifiers).
But that gives us ACA and not just ACA$_0$. I am aware that ACA proves Con(PA) unlike ACA$_0$, so ACA is strictly stronger. At the same time $Π^1_1$-CA$_0$ is strictly stronger than ACA$_0$ and also proves Con(PA), but is it strictly stronger than ACA? I guess I am asking a well-known question with a well-known answer, but I do not know how to find it.