Firstly, your lemma is false. The true lemma is if there exists some $t_0>0$ and $0<\alpha<1$ such that $\mathbb{P}_x(\tau_A \leq t_0) \geq \alpha$, then $\mathbb{E}_x(\tau_A) \leq \frac{t_0}{\alpha}$.
Your idea works. Note that $\mathbb{P}_x(\tau_A \leq t_{mix}) \geq P^{t_{mix}}(x,A)$. On the other hand $\left |{P^{t_{mix}}(x,A)-\pi(A)}\right |\leq d(t_{mix})<\frac{1}{4}$, which implies $P^{t_{mix}}(x,A)>\pi(A)-\frac{1}{4}$. Then $\mathbb{P}_x(\tau_A \leq t_{mix})>\pi(A)-\frac{1}{4}$. If $\pi(A)-\frac{1}{4}\leq 0$, the inequallity that we want to prove is obvious. If $\pi(A)-\frac{1}{4}>0$, we will use your lemma to say that $\mathbb{E}_x(\tau_A) \leq \frac{t_{mix}}{\pi(A)-\frac{1}{4}}$, which implies $t_{mix} \geq \left(\pi(A)-\frac{1}{4} \right)\mathbb{E}_x(\tau_A)$, and finally we maximize the right part over all $x \in \Omega$ and $A \subseteq \Omega$, and we finish the proof.