$f(x) = 2e^x - \frac14e^{2x}$
$f'(x) = 2e^x - \frac 14e^{2x}*2 = 2e^x - \frac 12e^2x$
$f''(x) = 2e^x - e^2x; f''(x) = 0 \iff x = \ln 2$
$f'''(x) = 2e^x - 2e^{2x}; x = \ln 2 \implies f'''(x) = 2*2-2(2^2) < 0$
$f''(\ln 2) = 0 \implies x=\ln 2; f'(\ln 2) = 2*2 - \frac 12 2^2 = 2; f(\ln 2) = 2*2 -\frac 14 2^2 = 3$ is an extrema for $f'(x)$; the slope of $f(x)$.
$f'''(\ln 2) < 0 \implies x=\ln 2; f'(\ln 2) = 2$ is a maximum value for $f'(x)$; the slope of $f(x)$.
So the sharpest tangent line is at $x_0 = \ln 2$ where the slope is $f'(\ln 2)=2$ so the equation of the line is:
$y- f(x_0) = f'(x_0)(x - x_0)$
$y - 3 = 2(x-\ln 2)$
$y = 2x - 2\ln2 + 3$
So what did you do wrong? You confused "$x = \ln 2$ so slope $= f'(x)= 2$" with "$x = \ln 2$ so slope $ = x = 2$", apparently.