Following up on the previous answer, any method you chose you should arrive at the same result for the derivative with respect to a.
For notation purposes, let's say $F(a)=\int_0^1 \! \frac{{e^{-ax}}\sin(x)}{x} dx$. Now:
$$F'(a)=-\int_{0}^{1}\!e^{-ax}\sin(x) \, \mathrm{d}x=\frac{e^{-a}(\cos(1)+a\sin(1))}{a^2+1}-\frac{1}{a^2+1}$$
In order to recover $F(x)$ we need to integrate that... The second term integrates to $\tan^{-1}(a)$, but the first term is not solvable in terms of elementary functions, wolfram says it is the following:
$$F(a)=\int \frac{e^{-a}(\cos(1)+a\sin(1))}{a^2+1} da=\frac{1}{2}[i \space Ei(-a-i)-i\space Ei(i-a)]+C$$
For the constant term, set $a=0$, and equate to find $C=-\frac{\pi}{2}$, giving$$F(a)=\frac{1}{2}[i \space Ei(-a-i)-i\space Ei(i-a)]+\tan^{-1}(a)-\frac{\pi}{4}$$
In order to evaluate that, setting $a=0$, the tangent term vanishes, and we are left with the following:
$$\frac{1}{2}[i \space Ei(-i)-i\space Ei(i)]=\frac{1}{2}[i\int_1^{\infty}\frac{e^{-t(-i)}}{t}dt-i\int_1^{\infty}\frac{e^{-t(i)}}{t}dt]$$ Getting both integrals together, and using $\frac{i}{2}=\frac{-1}{2i}$, we arrive at the following expression:$$-\int_{1}^{\infty}\frac{\frac{e^{it}-e{-it}}{2i}}{t}dt=-\int_1^{\infty}\frac{\sin(t)}{t}dt$$ which is the complementary sine integral evaluated at 1, and since the area under the positive real axis of that function is $\pi/2$, then the integral becomes $\pi/2-Si(1)$, where $Si(x)$ is the Sine integral.
And since $F(0)$ as we originally defined it $is$ the Sine integral evaluated at 1, then $c=\frac{\pi}{2}$.
I really hope this helps in some way... Could I ask what you needed to know the answer for? And if anyone has a better approach at evaluating these sort of integrals i'd be glad to know it.