Let $x $ ~ $ y $ $:\iff$$x\leq y\lor y\leq x$
and $x,y\in M$ and $M$ is an ordered set.
I think this does define an equivalence relation with only one equivalence class.
Proof:
Reflexive:$x$~$x$
$x\leq x$
Symmetric:$x$~$y$ $\implies$$y$~$x$
If $x\leq y$ $\implies$ $y\geq x$
If $x\geq y$ $\implies$ $y\leq x$
Transitive:$x$~$y$ $\land$ $y$~$z$ $\implies$$x$~$z$
$x\leq y\lor y\leq x$ $\land$ $y\leq z\lor y\leq z$ $\implies$ $x\leq z\lor z\leq x$