Here is my tuppence worth. I hope it is what you are after and please excuse the perhaps unfamiliar notation - comments/questions/suggestions are welcome!
Let $M$ be a Riemannian manifold endowed with metric $g$ where
$$g \,=\, \delta_{ab}e^{a} \otimes e^{b}$$
with respect to a $g$-orthonormal coframe $\{e^{a}\}$. Denote the dual $g$-orthonormal frame $\{X_{b}\}$ (i.e. $e^{a}(X_{b})=\delta^{a}_{b}$). We introduce the operator
$$A_{X} \,\equiv\, \nabla_{X} - \mathcal{L}_{X}\quad \text{for any}\; X\in TM$$
in terms of the Levi-Civita connection $\nabla_{X}$ and Lie derivative $\mathcal{L}_{X}$. Note that since $\nabla_{X},\mathcal{L}_{X}$ commutes with contractions, so does $A_{X}$, and that for any function $f$ it should be clear that $A_{X}f=0$. In particular, for any $X,Y,Z\in TM$:
$$\begin{align}A_{X}[\,g(Y,Z)\,] \,=\, 0 &\,=\, (A_{X}g)(Y,Z) + g(A_{X}Y,Z) + g(Y,A_{X}Z) \\
&\,=\, -(\mathcal{L}_{X}g)(Y,Z) + g(A_{X}Y,Z) + g(Y,A_{X}Z),
\end{align}$$
since $\nabla$ is metric compatible. Furthermore, since $\nabla$ is torsion-free, we can show $A_{X}Y=\nabla_{Y}X$. Putting all this together yields
$$(\mathcal{L}_{X}g)(Y,Z) \,=\, g(\nabla_{Y}X,Z) + g(Y,\nabla_{Z}X)$$
for any $X,Y,Z\in TM$. In particular, for $V\in TM$:
$$\begin{align}
(\mathcal{L}_{V}g)(X_{k},X_{k}) \,=\, tr_{g}(\mathcal{L}_{V}g) &\,=\, g(\nabla_{X_{k}}V,X_{k}) + g(X_{k},\nabla_{X_{k}}V) \,=\, 2\,i_{X_{k}}\nabla_{X_{k}}\widetilde{V}
\end{align}$$
where $\widetilde{X}=g(X,-)$ denotes the metric dual of any $X\in TM$ (we use the metric compatibility of $\nabla$ to get here). Thus we have
$$i_{X_{k}}\nabla_{X_{k}}\widetilde{V} \,=\, \frac{1}{2}tr_{g}(\mathcal{L}_{V}g)$$
Now for torsion-free $M$, we have
$$de^{a} + \omega^{a}_{\;b} \wedge e^{b} \,=\, 0$$
in terms of the connection 2-forms $\{\omega^{a}_{\;b}\}$ defined by:
$$\nabla_{X_{b}}e^{a} \,=\, -\omega^{a}_{\;c}(X_{b})e^{c}.$$
It is easy to show using these two relations that $d\equiv e^{a} \wedge \nabla_{X_{a}}$. Then using $\text{div}(V)=\star d\star \widetilde{V}$ in terms of the Hodge map $\star$:
$$\text{div}(V) \,=\, \star d\star \widetilde{V} \,=\, \star(e^{k} \wedge \nabla_{X_{k}}\star\widetilde{V}) \,=\,i_{X_{k}}\nabla_{X_{k}}\widetilde{V} \,=\, \frac{1}{2}tr_{g}(\mathcal{L}_{V}g) $$
where again you use the metric-compatibility of $\nabla$ to commute it with the Hodge map: $\nabla_{X}\,\star=\star\nabla_{X}$.
NB: If you are familar with it, you may notice that the object $i_{X_{k}}\nabla_{X_{k}}$ is, up to possibly a sign, related to the co-derivative $\delta$ on $M$. It should also be noted that most of this, again up to a possible sign, follows through for pseudo-Riemannian manifolds.