First, recall that the dimension of a vector space is the number of vectors in a basis for it. Be careful to distinguish between the dimension of the total space that you’re working in from that of its subspaces. The former, $\mathbb R^3$, is indeed three-dimensional, but its subspaces can be of any dimension from $0$ to $3$.
So, for instance, even though the elements of $S$ are coordinate triples, the dimension of $S$ is at most two, because it’s generated by only two vectors. It’s exactly two if the vectors are linearly independent, in which case they form a basis for $S$.
On to the problem at hand. Start by plugging the two vectors that generate $S$ into the defining equation for $V$: $$\begin{align}1-1-0&=0 \\ 5-2-3&=0.\end{align}$$ Both of the vectors thus satisfy this equation, and so any linear combination of them will also satisfy the equation (try it!). This shows that $S\subseteq V$.
To prove equality, you need to show either that $\dim S=\dim V$ or that $V\subseteq S$. For the former, you might start be finding out whether or not the two vectors that generate $S$ are linearly independent (for a pair of vectors that’s really easy). That’ll tell you if $\dim S$ is $1$ or $2$, after which you’ll need to work out the dimension of $V$ and compare them. I’ll leave the details for you to work out.
If you want to try to prove $V\subseteq S$ instead, one approach is to first characterize the elements of $V$ in a different way. The defining equation of $V$ is $x-y-z=0$, so $V$ clearly consists of all elements of $\mathbb R^3$ of the form $(y+z,y,z)$. (This can also help you figure out the dimension of $V$, by the way.) Now, can you express such a vector as a linear combination of $(1,1,0)$ and $(5,2,3)$? In other words, solve $$(y+z,y,z)=\alpha(1,1,0)+\beta(5,2,3)=(\alpha+5\beta,\alpha+2\beta,3\beta)$$ for the scalars $\alpha$ and $\beta$. This will show that $(y+z,y,z)\in S$, and so $V\subseteq S$. Again, I leave working out the details to you.