Show that $G$ is doubly transitive on $\Omega$ if $\dfrac{1}{|G|}\sum_{g\in G} \chi(g)^2=2$ where $\chi$ is the associated permutation character. Do not assume $G$ is transitive.
An action of $G$ on $\Omega$ is doubly transitive if $G$ is transitive on the set of ordered pairs $(\alpha,\beta)$ with $\alpha\neq \beta$ with $$(\alpha,\beta)\cdot g=(\alpha\cdot g, \beta\cdot g).$$
I know by the Cauchy-Frobeius Theorem that the total number of orbits is given by $$n=\dfrac{1}{|G|}\sum_{g\in G} \chi(g).$$
But where do I go from here?