1)I try to show that the graphs with total chromatic number $\chi''(G)=\chi'(G)+\chi(G)$ are exactly the bipartite graphs.
Definition https://en.wikipedia.org/wiki/Total_coloring
After the answer of Smylic
2)If $\chi''(G)=\chi'(G)+\chi(G)$ holds then the graph should be bipartite