Referring to your comment above, I will prove that $\frac{1}{t} \int_0^t T_s \mu \; ds$ does not converge weakly to any measure as $t \to \infty$.
First, changing variables with $u=t^{-1/2}(y-x)$ gives $$P_t(x,A) = (2\pi)^{-d/2} \int_{\Bbb R^d} e^{-|u|^2/2}1_{[t^{-1/2}A+x]}\;du$$
Since $1_{[t^{-1/2}A+x]} \to 0$ pointwise as $t \to \infty$ for any bounded borel set $A$, the dominated convergence theorem tells us that $P_t(x,A) \to 0$ as $t \to \infty$ for any bounded Borel set $A$. It follows that the Cesaro means $t^{-1}\int_0^t P_s(x,A)ds$ also converge to zero as $t \to \infty$.
By applying Fubini's theorem, we see that for any probability measure $\mu$ on $\Bbb R^d$ and any bounded Borel set $A$, $$t^{-1}\int_0^t (T_s\mu)(A)ds = \int_{\Bbb R^d} \bigg(t^{-1}\int_0^tP_t(x,A)ds \bigg)\mu(dx) \stackrel{t\to \infty}{\longrightarrow} 0$$ where the final limit is obtained by our preceding observations and the dominated convergence theorem (which is justified since the integrand is bounded above by $1$, which is $\mu$-integrable since $\mu$ is a probability). This proves the claim.
Remark: What this conclusion basically means is that there is no invariant probability measure for the heat semigroup (i.e, for Brownian motion) on $\Bbb R^d$. However, as you may easily check, there are certainly invariant measures which are non-probability, for instance Lebesgue measure.