Funny you should ask that because these issues were just discussed in my statistics class this morning. Let's think about what is happening which will help us perceive the subtle difference between the binomial and the geometric distributions.
Binomial
We have a set $A$ of five elements, for which each $A_i \in \{\text{W}, \text{Q} \}$ where $\text{W}$ denotes a white marble and $\text{Q}$ denotes a marble of any other color.
In the first case, the random variable is the number of marbles in a taking of $n$ marbles. There are a total of $\binom{5}{1}=5$ outcomes, i.e. the white marble can fall in the first, second, third, fourth, or fifth draw. Each one of these five outcomes has probability $(1-p)^4p$ if $p$ is the probability of a marble being drawn. Thus, we can represent the total probability of there being a white marble as the sum of the probabilities of each outcome for which there is exactly one white marble in a group of five marbles.
$$P(\text{one white marble in five}) = \sum^{5 \text{ outcomes}}{(1-p)^4p} = 5(1-p)^4p$$
Geometric
Now let's analyze the second case you describe which is subtly different. Here, we are not interested in knowing the probability that, given $n$ trials I will find a white marble. Instead, the random variable $X$ is the number of trials it will take until a white marble is found. More abstractly, we are measuring the probability there will be no white marbles in the first $x-1$ picks and then exactly one white marble in the $x$th pick. The probability of there being no white marbles in the first $x-1$ picks is $(1-p)^{x-1}$ and the probability of there being a white marble in the $x$ pick is $p$. Thus
$$P(X=x) = (1-p)^{x-1}p$$
What is the difference?
The random variables are simply different. We are answering two different questions.
The Punch Line
We know the probability of the first white marble appearing in $n$ trials. We also know the probability of observing $1$ white marble in $n$ trials.
It is five times less likely the first white marble will appear in the 5th trial than it will appear in any of the first to the fifth trials. This makes sense.
The white marble can appear in any of our five picks. The binomial distribution cares about the likelyhood the white marble will appear in ANY of the five picks, i.e. any of the configurations in which one white marble can appear in a set of five marbles. The geometric distribution cares about the likelihood the white marble appears in ONLY ONE of the five configurations that the binomial distributions accounts for, namely, the last one.
I hope this made it a little clearer to you.