As the first answer in a link shown , $T\sim {\rm Gamma}(2,1), S\sim {\rm Exp}(1)$, we have two properties:
$T-S\sim {\rm Exp}(1)$,
$T-S$ is independent of $S$.
I cant prove them. Esperically for Question 1, I find that,
$Z = T-S$,
${\rm pdf}(z)=\dfrac{1}{4}e^{z}$.
Obviously, Z does not conform to ${\rm Exp}(1)$. So I am not sure where it is wrong.
Thank you very much!