Your function is positive, so it must be increasing, as must be the derivative $f'(x)$. If we look at $f(x+2) - f(x) \lt f(x+5) - f(x+3)$
we see that we can write this as
$$f(x+2) - f(x) \lt f(v+2) - f(v)$$
We can now use the fact that $xx$, the RHS must be greater than the LHS.
Think of it this way: since the derivative is increasing, we know that the farther we go to the right the faster the function is growing. What we are looking at with the subtraction is the difference in heights between points separated by two, which is pretty small at first but gets larger and larger. If you want a visual, imagine $f'(x) = x^2$ and try drawing the heights.
Proof
First of all, note that $f''(x)>0 \implies f'(x)$ is increasing, and let $v=x+3$ as above
Note that we can use the Mean Value Theorem on both $x$ and $v$
$$2f'(c_v) = f(v+2)-f(v)$$
$$2f'(c_x) = f(x+2)-f(x)$$
We note that
$$v = x+3 < c_v < v+2 = x+5 \implies 3 < c_v - x < 5$$
$$v = x < c_x < x+3 \implies 0 < c_x - x < 2$$
Now, the inequalities above show that $c_v-x > c_x-x \implies c_v > c_x$. We also know that, since $f'(x)$ is increasing, $a