Without the word "connected" the answer is the disjoint union of a triangle and a square, per Smallest Graph that is Regular but not Vertex-Transitive?
I also know per wikipedia that the Frucht graph is a connected example with twelve vertices.
Without the word "connected" the answer is the disjoint union of a triangle and a square, per Smallest Graph that is Regular but not Vertex-Transitive?
I also know per wikipedia that the Frucht graph is a connected example with twelve vertices.
The smallest example surely has $\leq \color{red}{8}$ vertices.
The depicted graph is a planar cubic graph, but is not vertex-transitive: there are three pentagonal faces meeting at the central point, and the central point is the only vertex with such a property. By a similar principle, here it is an example with $8$ vertices:
Some vertices belong to triangular faces, some don't.