Depends on what you mean by "point away" (consider the zero matrix, which consists of zero vectors, all "pointing" in arbitrary directions).
Otherwise, you are partially correct. In general, if an $n$ by $n$ determinant is 0, it simply means that the column vectors do not span Rn. This does not necessarily mean that they need to meet in one line.
Let us look at the 3 by 3 case. We do not need to consider the row vectors, since we know they span a vector space with the same dimension as the column vectors. So, if the column vectors span a plane, then the row vectors do so as well.
Now, if the determinant is 0, this could mean one of the following:
- Two column vectors are parallel (and can be placed on the same line) and the third one, together with one of the parallel vectors, span a plane in R3.
- All three column vectors are parallel, and can be placed on a line, as you suggested. In this case, they span a line.
Hope this helped.