Case 1 -
Two dices each with a probability of rolling 6 at 1 / 6th. Since you need just one of them to be 6. Total probablility is
$$\frac{1}{6} + \frac{1}{6} + \frac{1}{6} + \frac{1}{6} = \frac{2}{3}$$
$$66.66\%$$
There is a 66.66% probability that one of your two dices will roll a six.
Case 2 -
2 dices rolled 24 times,
number of combinations / roll is given by $\frac{1}{6^{2}}$ since we have 6 possibilities and each with a combination of six more possibilities on die two. Do this 24 times and total probability becomes.
$$=24 * \frac{1}{6^{2}}$$
$$=\frac{3}{4}$$
$$=75\%$$
There is a 75% probability that one of your 24 rolls will result in a 1,1 roll.
Case 2 has a higher probability.
Edit: If you feel my answer is wrong I'd like to know why?