The proof by Jordan blocks is fine, although it needs a bit of care as we are working over $\mathbb{R}$ and not $\mathbb{C}$.
But the result is far less deep than that.
Look at the Laplace expansion of the determinant whose entries $a_{ij}(t)$ depend on $t$. When we differentiate this, each of the products is replaced by a sum of $n$ terms got by differentiating the various factors. Gathering up the terms sensibly it is clear that the derivative is the sum of $n$ determinants, each got by replacing a row of the original determinant by its derivative $a'_{ij}(t)$.
Now all is easy; in the case at hand only the diagonal entry gives a non-zero derivative, and that derivative is $1$. (I use @Vincent's sensible suggestion that it is always better to look at $tI-A$).