$w = e^{bi}$ for $0 \le b \le 2\pi$ traverses the unit circle. You then transform that unit circle by $f(w) = \frac{2ew-3}{3ew-2}$, which is a Möbius transformation. One of the basic properties of these is that they take circles to circles (or straight lines, in the case where a point of the first circle is a root of the denominator). In this case $3ew-2=0$ for $w = 2/(3e)$, which is not on the unit circle, so it is indeed a circle. Now, which circle?
The first thing to notice is that, because complex conjugation takes the unit circle to itself, and $f(\overline{w}) = \overline{f(w)}$, the complex conjugation takes the image circle to itself. That says the centre must be on the real line. Now two points of the circle on the real line are $f(1) = (2e-3)/(3e-2)$ and $f(-1) = (-2e-3)/(-3e-2) = (2e+3)/(3e+2)$. Thus the centre must be the midpoint of these, namely $$ \frac{6(e^2-1)}{9 e^2-4}$$