Given any vector $v=(a,b)$ in ${\bf R}^2$, its length $r$ is given by the formula $r=\sqrt{a^2+b^2}$. If $v$ is not the zero vector, then $(a/r,b/r)$ is a unit vector in the direction of $v$. Then $\{\,(a/r,b/r),(b/r,-a/r)\,\}$ is an orthonormal basis for ${\bf R}^2$ (with respect to the usual inner product). Moreover, every orthonormal basis for ${\bf R}^2$ is of that form, or of the form $\{\,(a/r,b/r),(-b/r,a/r)\,\}$.
Given any vector $v=(a,b)$ in ${\bf C}^2$, its length $r$ is given by the formula $r=\sqrt{|a|^2+|b|^2}$. If $v$ is not the zero vector, then $(a/r,b/r)$ is a unit vector in the direction of $v$. Then $\{\,(a/r,b/r),(\bar b/r,-\bar a/r)\,\}$ is an orthonormal basis for ${\bf C}^2$ (with respect to the usual inner product). Moreover, every orthonormal basis for ${\bf C}^2$ is of that form, or of the form $\{\,(a/r,b/r),(-\bar b/r,\bar a/r)\,\}$.
Here, $\bar w$ denotes the complex conjugate of the complex number $w$.