So Rudin defines $|f| \in \mathscr{R}(\alpha) \iff \underline \int_{a}^{b} |f| \,d\alpha = \overline \int_{a}^{b} |f| \,d\alpha$.
There's a Theorem which states: $\underline \int_{a}^{b} f \,d\alpha \leq \overline \int_{a}^{b} f \,d\alpha$, which gives us: $\underline \int_{a}^{b} |f| \,d\alpha \leq \overline \int_{a}^{b} |f| \,d\alpha$.
So: we are left to show that $\overline \int_{a}^{b} |f| \,d\alpha \leq \underline \int_{a}^{b} |f| \,d\alpha $.
Proof: Indeed, since $f \in \mathscr{R}(\alpha)$, it satisfies the Riemann condition on $[a,b]$ so that:
$U(f,\alpha;P) \leq L(f,\alpha;P) + \epsilon \leq L(|f|,\alpha;P) + \epsilon \leq \underline \int_{a}^{b} |f| \,d\alpha + \epsilon.$
Since $-|f(x)| \leq f(x) \leq |f(x)|,$ we have that: $U(-|f|,\alpha;P) \leq U(f,\alpha;P) \leq U(|f|,\alpha;P)$. So at best, I can say:
$ - \overline \int_{a}^{b} |f| \,d\alpha \leq U(-|f|,\alpha;P) \leq U(f,\alpha;P) \leq \cdots \leq \underline \int_{a}^{b} |f| \,d\alpha + \epsilon. $
I've been stuck here for a while now. I'm not sure if I have reached a dead-end or if I'm close, but I have no idea how to proceed from here. Any and all help is very greatly appreciated. Thanks!