I'm gonna prove if $x$ is not free in $\psi$, then $(\phi \rightarrow \psi)\models (\exists x \phi \rightarrow \psi) $.
Here is my argument:
According to definition of rule of inference of QR, if $x$ is free, then one can deduce $(\exists x \phi \rightarrow \psi)$ from $\phi \rightarrow \psi$. Mathematically: $(\phi \rightarrow \psi)\vdash (\exists x \phi \rightarrow \psi) $. Furthermore, from soundness theorem, we know that, if $a \vdash b$ then $a \models b$. So, according to truth of $(\phi \rightarrow \psi)\vdash (\exists x \phi \rightarrow \psi) $, $(\phi \rightarrow \psi)\models (\exists x \phi \rightarrow \psi) $ holds.
Is this sort of argument valid?
If one says (you must prove that "if $x$ is free, then one can deduce $(\exists x \phi \rightarrow \psi)$ from $\phi \rightarrow \psi$", I don't know the argument for that.)
UPDATE:
$(\phi \rightarrow \psi) \models (\exists x \phi \rightarrow \psi)$
$(\phi \rightarrow \psi) \models \neg(\exists x \phi) \vee \psi$
$(\phi \rightarrow \psi) \models (\forall x (\neg \phi)) \vee \psi$
$(\neg\phi \vee \psi) \models (\forall x (\neg \phi)) \vee \psi$
$(\neg\phi \vee \psi) \models (\forall x (\neg \phi)) \vee \psi$
By universal instantiation:
$(\neg\phi \vee \psi) \models (\neg \phi) \vee \psi$
Which is true.
