Here is a proof of your second question.
Consider a set $E$ containing $n$ elements ($\mathrm{card}(E)=n$) and $q=\mathrm{card}(F)$ where :
$$F=\{(A,B)\in\mathcal{P}(E)^2;\,A\cap B=\emptyset\}$$
Since the single subset $A$ of $E$ verifying $A\cap A=\emptyset$ is $\emptyset$ itself, the answer to your question will be $1+\frac{q-1}{2}$.
Since the elements of $F$ can be classified according to their cardinal, we have :
$$F=\bigcup_{k=0}^nF_k\qquad\mathrm{where}\quad F_k=\{(A,B)\in\mathcal{P}_k(E)^2;\,A\cap B=\emptyset\}$$
where $\mathcal{P}_k(E)$ denotes the set of all subsets of $E$ whose cardinal is $k$.
This is the union of pairwise disjoint sets, and therefore :
$$q=\sum_{k=0}^n\mathrm{card}(F_k)$$
We see that $\mathrm{card}(F_k)={n\choose k}2^{n-k}$. Thus :
$$q=\sum_{k=0}^n{n\choose k}2^{n-k}=3^n$$
Finally, there are $1+\frac{3^n-1}{2}$ unordered pairs of disjoint subsets.