OK, so you need 2 days of rain, and 4 days of not rain.
First: when are those days? It could be the first two days, but it could also be the first and third day, or fourth and sixth day, etc. Now, the choose function is exactly what you want here: out of these 6 days, you want to choose exactly 2. That is: there are $6 \choose 2$ possible such pairings.
Second, once we focus on a specific pairing, e.g. rain on the first two days, and not rain on the last four, we can say that the probability that that happens is:
$0.8*0.8*0.2*0.2*0.2*0.2 = (0.8)^{2}*(0.2)^4$
But the same is true for any other pairing, e.g. to get rain on the fourth and sixth day, and not the others, we get:
$0.2*0.2*0.2*0.8*0.2*0.8 = (0.8)^{2}*(0.2)^4$.
So, each such specific pairing happens with a probability of $(0.8)^{2}*(0.2)^4$.
Finally, we get:
P(rain on exactly two days) =
P(rain on first two days or rain on first and third day or ...) =
P(rain on first two days) + P(rain on first and third day) + ... =
${6} \choose {2}$ * $(0.8)^{2}*(0.2)^4$