There's only one way in general: plug in a number and see what you get. If $f(x) > g(x)$ for that value of $x$, then $f$ will be larger than $g$ until they intersect again. I assume, though, that you're looking for something simpler, something you could use when $f$ and $g$ are hard to compute. The answer is that there isn't any technique that will work all the time - there's just a few tricks you can use in specific cases.
For example, in your image you're looking at the functions $f(x) = x^2$ and $g(x) = \sqrt{x}$. When $x$ is very small (very close to zero), $x^2$ is very small (a very small piece of a very small number) while $\sqrt{x}$ is "smallish" (only its square is "very small"). So $\sqrt{x} > x^2$ when $x$ is a little bigger than zero, and it will remain that way until the curves intersect again (at $x = 1$).