The expression for $W_{1/2}$ you wrote down is part of one approach to constructing Brownian motion on $[0,1]$. You asked about $W_1.$ $W_1$ is constructed before $W_{1/2}$ so its value can be used to construct $W_{1/2}.$ The definition of $W_1$ is likewise in terms of $W_0$ (which is usually taken to be zero). The definition is $$W_1 = W_0 + Z_1$$ where $Z_1$ is a standard normal.
After $W_1$ is defined, we define $W_{1/2}$ in terms of $W_0$ and $W_1$ as $$ W_{1/2} = \frac{W_0 +W_1}{2} + \frac{1}{2}Z_2$$ where $Z_2$ is a standard normal independent from $Z_1.$ From this definition we can see that the three values we have constructed are consistent the axioms of Brownian motion. Namely, $W_1-W_0=Z_1$ is $N(0,1)$ and $W_{1/2}-W_0$ and $W_1-W_{1/2}$ are independent $N(0,1/2)$ 's. (They come out to $(Z_1+Z_2)/2$ and $(Z_2-Z_1)/2$, which fit the bill.) Then you could go on to define $W_{1/4}$ and $W_{3/4}$ in terms of the other values and new independent normals $Z_3$ and $Z_4.$ And then the eighths and sixteenths, etc.
That's all well and good, but it looks like you have a simpler problem of calculating some expected values. For this, you just need one of the basic properties of Brownian motion: $W_t$ is distributed as $N(0,t).$ So in your case $W_{1/2}$ is $N(0,1/2)$ so has PDF $$ f(x) = \frac{1}{\sqrt{\pi}}e^{-x^2}$$
So $$ E(W_{1/2}^6) = \int_{-\infty}^\infty x^6\frac{1}{\sqrt{\pi}}e^{-x^2}dx = \frac{15}{8}$$ and $$ E(e^{W_{1/2}}) = \int_{-\infty}^\infty e^x\frac{1}{\sqrt{\pi}}e^{-x^2}dx = e^{1/4}.$$