An idea is to begin seperating the real and imaginary parts (this was too long to put in a comment). Use:
$$\exp\left[-\text{a}\cdot\left(\sigma+\zeta i\right)\right]=\exp\left[-\text{a}\sigma\right]\cdot\exp\left[-\text{a}\zeta i\right]=\frac{\cos\left(\text{a}\zeta\right)-\sin\left(\text{a}\zeta\right)i}{\exp\left[\text{a}\sigma\right]}\tag1$$
So, we get for the LHS:
1.$$\Re\left(\text{A}\cdot\text{a}\cdot e^{-\text{a}\cdot\text{T}}\right)=\Re\left\{\text{A}\cdot\text{a}\cdot\frac{\cos\left(\text{a}\zeta\right)-\sin\left(\text{a}\zeta\right)i}{\exp\left[\text{a}\sigma\right]}\right\}=\text{A}\cdot\text{a}\cdot\frac{\cos\left(\text{a}\zeta\right)}{\exp\left[\text{a}\sigma\right]}\tag2$$
2.$$\Im\left(\text{A}\cdot\text{a}\cdot e^{-\text{a}\cdot\text{T}}\right)=\Im\left\{\text{A}\cdot\text{a}\cdot\frac{\cos\left(\text{a}\zeta\right)-\sin\left(\text{a}\zeta\right)i}{\exp\left[\text{a}\sigma\right]}\right\}=-\text{A}\cdot\text{a}\cdot\frac{\sin\left(\text{a}\zeta\right)}{\exp\left[\text{a}\sigma\right]}\tag3$$
Now, for the RHS:
$$\frac{2i}{3\cdot\Re\left(\text{T}\right)}\cdot\left(\omega_0+\text{A}\cdot e^{-\text{a}\cdot\text{T}}\right)=\frac{2i}{3\cdot\sigma}\cdot\left(\omega_0+\text{A}\cdot\frac{\cos\left(\text{a}\zeta\right)-\sin\left(\text{a}\zeta\right)i}{\exp\left[\text{a}\sigma\right]}\right)=$$
$$\frac{2}{3\cdot\sigma}\cdot\left(\omega_0i+\text{A}\cdot\frac{\sin\left(\text{a}\zeta\right)+\cos\left(\text{a}\zeta\right)i}{\exp\left[\text{a}\sigma\right]}\right)\tag4$$
So, we can write:
1.$$\Re\left\{\frac{2i}{3\cdot\Re\left(\text{T}\right)}\cdot\left(\omega_0+\text{A}\cdot e^{-\text{a}\cdot\text{T}}\right)\right\}=\frac{2}{3\cdot\sigma}\cdot\left(\text{A}\cdot\frac{\sin\left(\text{a}\zeta\right)}{\exp\left[\text{a}\sigma\right]}\right)\tag5$$
2.$$\Im\left\{\frac{2i}{3\cdot\Re\left(\text{T}\right)}\cdot\left(\omega_0+\text{A}\cdot e^{-\text{a}\cdot\text{T}}\right)\right\}=\frac{2}{3\cdot\sigma}\cdot\left(\omega_0+\text{A}\cdot\frac{\cos\left(\text{a}\zeta\right)}{\exp\left[\text{a}\sigma\right]}\right)\tag6$$
So, we can set up a system of equations:
$$
\begin{cases}
\text{A}\cdot\text{a}\cdot\frac{\cos\left(\text{a}\zeta\right)}{\exp\left[\text{a}\sigma\right]}=\frac{2}{3\cdot\sigma}\cdot\left(\text{A}\cdot\frac{\sin\left(\text{a}\zeta\right)}{\exp\left[\text{a}\sigma\right]}\right)\\
\\
-\text{A}\cdot\text{a}\cdot\frac{\sin\left(\text{a}\zeta\right)}{\exp\left[\text{a}\sigma\right]}=\frac{2}{3\cdot\sigma}\cdot\left(\omega_0+\text{A}\cdot\frac{\cos\left(\text{a}\zeta\right)}{\exp\left[\text{a}\sigma\right]}\right)
\end{cases}\tag7
$$
This leads towards, this simplified system of equations:
$$
\begin{cases}
\text{a}\cdot\frac{\cos\left(\text{a}\zeta\right)}{\exp\left[\text{a}\sigma\right]}=\frac{2}{3\cdot\sigma}\cdot\frac{\sin\left(\text{a}\zeta\right)}{\exp\left[\text{a}\sigma\right]}\\
\\
\frac{\sin\left(\text{a}\zeta\right)}{\exp\left[\text{a}\sigma\right]}=-\frac{1}{\text{A}\cdot\text{a}}\cdot\frac{2}{3\cdot\sigma}\cdot\left(\omega_0+\text{A}\cdot\frac{\cos\left(\text{a}\zeta\right)}{\exp\left[\text{a}\sigma\right]}\right)
\end{cases}\tag8
$$
So:
$$\text{a}^2\cdot\frac{\cos\left(\text{a}\zeta\right)}{\exp\left[\text{a}\sigma\right]}=-\frac{4}{9\cdot\sigma^2}\cdot\left(\frac{\omega_0}{\text{A}}+\frac{\cos\left(\text{a}\zeta\right)}{\exp\left[\text{a}\sigma\right]}\right)\tag9$$