Your inner product is defined like this
$$
\langle ., . \rangle : V \times V \to F
$$
for some vector space $V$ over some field $F$, two vectors from $V$ get a scalar from $F$ assigned.
Regarding your first equation:
$$
\langle x , a \rangle b = \langle xb,a\rangle
$$
A general inner product over complex numbers is
$$
\langle x, y \rangle = y^+ M x
$$
where $+$ is adjugation (not sure if this a correct English term), thus transposition and complex conjugation, and $M$ is some Hermitian positive-definite matrix, typically the identity matrix.
So
$$
\langle x , a \rangle b = (a^+ M x) b = a^+ M (xb) = \langle xb,a\rangle
$$
So your equality is true, where $x, a$ should be vectors from $V$, $b$ a scalar from $F$.
Regarding your second equation:
The second equation
$$
\langle xb,a\rangle = x\langle b,a \rangle
$$
is only true if $V = F$, otherwise $\langle b,a \rangle$ makes no sense.