I know that a graph is planar if and only if it contains no subgraph homeomorphic to $K_5$ or $K_{3,3}$, and I know that the Triakis Tetrahedral Graph is planar (http://mathworld.wolfram.com/TriakisTetrahedralGraph.html).
An additional edge added to the Triakis Tetrahedral will result in a non-planar graph (visually this is apparent). But what is the foundation of this? Is there now a $K_{3,3}$ subgraph? Is there an easy way to show which graphs can be superimposed to form this new graph (with the additional edge)?