Let $$f(z) = w=\frac{z+2i}{2iz-1}; \quad f^{-1}(w) = z=\frac{w+2i}{2iw-1}.$$
Here's one approach. You mentioned that you know Möbius transformations send the set of all circles and lines to itself. So, letting $U = \{w : |w| = 1\}$, you know that $f^{-1}(U)$ is either a line or a circle. You just need to figure out which of the two it is.
It is easy to tell the two apart: $3$ points on a line are collinear; $3$ points on a circle are not. Thus, we pick $3$ points $1, i, -i \in U$ and compute:
\begin{align*}
f^{-1}(1) &= [\text{compute me}] \\[7pt]
f^{-1}(i) &= \frac{i+2i}{-2 - 1} = -i \\[7pt]
f^{-1}(-i) &= \frac{-i + 2i}{2 - 1} = i
\end{align*}
Now it is clear that $f^{-1}(U)$ is a (line/circle), and moreover, it is the (line/circle) ...
In this problem, many stars aligned. In general, it won't be as nice to figure out what circle we're dealing with (lines are always nice). But it's a general fact that there's a unique circle through any $3$ non collinear points. It is a good exercise to find the center and radius for a circle going through $3$ non collinear points, or at least see why there is a unique such circle (draw a picture! Consider the perpendicular bisectors of line segments joining two pairs of points).