Since both D and E are symmetric 2x2 matrices
$$
\text{D}=\left(
\begin{array}{cc}
\text{$d_0$} & \text{$d_a$} \\
\text{$d_a$} & \text{$d_1$} \\
\end{array}
\right)
$$
$$
\text{E}=\left(
\begin{array}{cc}
\text{$e_0$} & \text{$e_a$} \\
\text{$e_a$} & \text{$e_1$} \\
\end{array}
\right)
$$
$DE$ is symmetric if and only if $(DE)^T=DE$ or:
$$
d_a e_1 + d_0 e_a=d_a e_0 + d_1 e_a \iff \frac{d_1-d_0}{d_a}=\frac{e_1-e_0}{e_a}
$$
then let's see what the Eigen Value equation implies:
$$
D\binom{1}{1}=\lambda\binom{1}{1} \iff \begin{cases}d_0+d_a=\lambda\\d_a+d_1=\lambda\end{cases} \implies d_0-d_1=0
$$
exactly the same argument applies to $E$ so
$$
e_0-e_1=0
$$
so by substitution the condition for $DE$ to be symmetric becomes:
$$
\frac{d_1-d_0}{d_a}=\frac{e_1-e_0}{e_a} \iff \frac{0}{d_a}=\frac{0}{e_a}\iff 0=0 \rm{\,\,\,\,\,which\,\, is\,\, true}
$$