Let $A,B,C,D$ be the vertices of the parallelogram with direct orientation, meaning that
$$\tag{0}\vec{AB}=\vec{DC}, \ \ \ \ \ \ \vec{AD}=\vec{BC}$$
(draw a figure!)
The line joining point $A$ to the midpoint $I$ of $BC$ has
$$\tag{1}\vec{AI}=\vec{AB}+\frac12 \vec{BC}$$
as its directing vector. We have to show that point $H$ defined by
$$\tag{2} \vec{AH}=\frac23 \vec{AI}$$
is such that
$$\tag{3}\vec{AH}=a\vec{AB} + (1-a) \vec{AD}$$
for a certain positive value $a$ ($H$, being on segment $BD$, is a weighted average of $B$ and $D$)
It shouldn't be difficult now, using (1),(2),(3) AND the second equation in (0), to get such an $a$.