Note: This question seems like it might have been asked before, but the poster deleted it and I don't have enough reputation to see it.
Let $V$ be a finite-dimensional real vector space. Such an object is, in a canonical way, a smooth manifold. Thus it makes sense to speak of smooth charts $(U,\varphi)$ for such a space (where $U \subseteq V$ is open of course). Let us restrict attention to those charts for which $U=V$.
Then if the chart function $\varphi: V \to \mathbb{R}^n$ is linear, each of its component functions (which I call coordinate functions, since each specifies a different coordinate of the chart) is a linear function $V \to \mathbb{R}$, thus an element of $V^*$.
(Obviously none of this works over arbitrary fields or for infinite-dimensional vector spaces, hence the restrictions I assume/gave above.)
Question: Thus, does it make sense to interpret or even define dual bases to be linear charts from $V$ to $\mathbb{R}^n$, and $V^*$ to be the space of all linear coordinate functions?
In particular, this would provide a ready explanation for why the components of a vector are written with the opposite index placement when using the Einstein summation convention. If $E = x^i E_i$ is a vector in $V$, then the components $x^i$ could be interpreted as short-hand for the evaluation of the linear coordinate functions (i.e. elements of $V^*$) evaluated at $E$ rather than just scalars, i.e. $$E = x^i(E) E_i \,.$$ Since the $x^i$ are elements of $V^*$, rather than scalars in $\mathbb{R}$, it becomes quite obvious why they should have the index placement they do.
Also components/linear coordinates transform the same way that dual vectors do under changes of basis (i.e. they are covariant), so thinking about vectors/dual spaces/tensors the way physicists do, interpreting components/linear coordinate functions as being the same thing as elements of $V^*$ seems to make a certain amount of sense. It might also make dual vector spaces easier to understand for those who tend to think physically or geometrically (e.g.).
However, I have not seen this practice mentioned in any texts on differential geometry or linear algebra which I have ever read, so I imagine that there are probably problems with it which I am not noticing or understanding yet.