Well, if you want to prove this properly, you need to use the definition of $>$. I will assume we know that there exists a subset $\Bbb P\subseteq\Bbb R$ (the set of real numbers) called the positive numbers which are closed under addition and multiplication, and that $\Bbb R$ satisfies the following:
Trichotomy: For any real number $r\in\Bbb R$, exactly one of the following is true:
- $r\in\Bbb P$,
- $-r\in\Bbb P$,
- $r = 0$.
Now, I will define what $a > b$ means.
Definition: Let $a$ and $b$ be real numbers. We say $a > b$ if and only if $a - b\in\Bbb P$. Write $a\geq b$ if either $a > b$ or $a = b$.
Finally, the proof.
Proof: Suppose that $a > b\geq 0$. I claim that $a > 0$; indeed, $a - b\in\Bbb P$, and either $b - 0 = b\in\Bbb P$ or $b = 0$. If $b = 0$, then $a - b = a$, so $a\in\Bbb P$. If $b\in\Bbb P$, then $(a - b) + b = a\in\Bbb P$, because $\Bbb P$ is closed under addition. Now, I claim that $a > b$ implies that $a^2 > ab$. This follows because $a - b$ and $a$ are both in $\Bbb P$, and so $a(a - b) = a^2 - ab\in\Bbb P$, as $\Bbb P$ is closed under multiplication as well. Similarly, $ab \geq b^2$ (you can verify this yourself, note that you need to consider the case $b = 0$ separately). So now we have $a^2 > ab\geq b^2$. We're almost done. $a^2 - ab\in\Bbb P$ and $ab - b^2\in\Bbb P$ or $ab - b^2 = 0$. If $ab - b^2\in\Bbb P$, then $(a^2 - ab) + (ab - b^2) = a^2 - b^2\in\Bbb P$, so $a^2 > b^2$. If $ab - b^2 = 0$, then $a^2 - b^2 = (a^2 - ab) + (ab - b^2) = a^2 - ab\in\Bbb P$, which is what we wanted to show.