Show $\{v_1, v_2 \}$ is Linearly Independent iff neither $v_1$ or $v_2$ is a multiple of each other. (where $v_1, v_2$ are vectors).
Going forward. Assume {$v_1, v_2$} is LI. Thus, if $c_1v_1 + c_2v_2 = 0$ $c_1 = c_2 = 0$. Assume for sake of contradiction that $v_1 = dv_2, d \in \mathbb{R}$. Thus $v_2 (c_2 + dc_1) = 0$, since $v_2 \ne 0$, it must be $c_2 + dc_1 = 0$ thus $d = c_2/-c_1$, but since $c_1 = c_2 = 0$, we get $d = 0/0$ undefined, contradiction.
The other direction, prove the contrapositive.
{$v_1, v_2$} is LD thus case where $c_1 = 0$ only, $c_2 = 0$ only, and both $c_1, c_2$ not zero.
Proving first two cases is trivial as we get $c_2v_2 = 0 = v_1$ and otherwise $c_1v_2 = 0 = v_2$.
Assume $c_1, c_2$ non zero, then we have $v_1 = -c_2/c_1v_2$, which is a multiple of $v_2$.
Is the proof complete?