Your question is: Can a given symmetric tensor of rank $1$ be written as a linear combination of other symmetric tensors of rank $1$? The answer is yes. Yes, a symmetric tensor of rank $1$ can be written as a linear combination of other symmetric tensors of rank $1$. This is true over the complex numbers, the real numbers, and other fields. For simplicity I'll write this answer over a field of characteristic zero; everything I say will be valid over real numbers and over complex numbers. (It can also be valid over other fields with mild conditions but I will ignore that for now.)
Before proceeding with generalities, perhaps a concrete example might be helpful? Let $V$ be a two-dimensional vector space with basis $x,y$. (You are welcome to think of this as $V = \mathbb{R}^2$ and $x = (1,0)$, $y=(0,1)$.) One of the symmetric tensors of rank $1$, and order $3$, in $V \otimes V \otimes V$, is $x \otimes x \otimes x$, which for short we might denote $x^3$. Can we write this $x^3$ as a linear combination of other rank $1$ symmetric tensors? Yes, in various ways; here is one.
$$
\begin{split}
(x+y) \otimes (x+y) \otimes (x+y) &= x \otimes x \otimes x + x \otimes x \otimes y \\
&\quad + x \otimes y \otimes x + y \otimes x \otimes x \\
&\quad + x \otimes y \otimes y + y \otimes x \otimes y \\
&\quad + y \otimes y \otimes x + y \otimes y \otimes y \\
&= x^3 + 3x^2y + 3xy^2 + y^3,
\end{split}
$$
where $x^3 = x \otimes x \otimes x$, $x^2y = \frac{1}{3}(x \otimes x \otimes y + x \otimes y \otimes x + y \otimes x \otimes x)$, and in general $xyz = \frac{1}{6}(x \otimes y \otimes z + \text{all permutations})$.
Well,
$$
(x+y)^3 + (x-y)^3 = x^3 + 6xy^2,
$$
and
$$
(x+2y)^3 + (x-2y)^3 = x^3 + 24xy^2 .
$$
So therefore
$$
4(x+y)^3 + 4(x-y)^3 - (x+2y)^3 - (x-2y)^3 = 3x^3.
$$
So the rank $1$ symmetric tensor $x^3$ is in the span of the $4$ rank $1$ symmetric tensors $(x \pm y)^3$ and $(x \pm 2y)^3$.
Now, this example begins to point the way to a more general answer. Because when we consider the space of symmetric tensors in $V \otimes V \otimes V$—it is a subspace that can be denoted $S^3 V$ ($S$ for Symmetric), or $S_3 V$, depending on the author—we see that it has dimension $4$. A basis is given by $x^3, x^2y, xy^2, y^3$. And another different basis is given by $(x\pm y)^3$, $(x \pm 2y)^3$. At that point it becomes clear that every symmetric tensor is a linear combination of those $4$ symmetric rank $1$ tensors, including all the symmetric rank $1$ tensors such as $x^3$.
So we have the first answer to your question: Let $V$ be any finite dimensional vector space. Let $d \geq 1$. Let $N$ be the dimension of $S^d V$. Now $S^d V$ is spanned by the symmetric rank $1$ tensors, so we can take some $N$ of them to form a basis. And now all the symmetric rank $1$ tensors can be written as linear combinations of those.
Now there is a reasonable follow-up question, which might perhaps be a natural question from a standpoint of an engineer who is interested in identifiability issues: Okay, if some symmetric rank $1$ tensor is equal to a linear combination of some $r$ other symmetric rank $1$ tensors, then what is $r$?
We can certainly have such linear combinations when $r=N$ (the dimension of $S^d V$) but unfortunately it can happen sooner than that. It happens as soon as $r=d+1$. Because if $V$ has a basis $x_1,\dotsc,x_n$, then $x_1^d$ can be written as a linear combination of $(x_1 + t_i x_2)^d$ for any (!) $d+1$ nonzero values of $t_i$. (Nutshell: with Vandermonde matrices you can show these are linearly independent, and there are enough of them to span all the degree $d$ polynomials in $x_1,x_2$, including $x_1^d$.)
I believe the converse may be true: if $L^d$ is a linear combination of some $r$ other symmetric rank $1$ tensors, then $r \geq d+1$. But at the moment I'm not sure where to find a result along those lines. (I looked in some papers of Reznick and the book of Iarrobino-Kanev; it might be in there somewhere but so far I have not been able to find it.) If you are interested, please let me know and I will be happy to resume the search.