EDIT: I just noticed you said first order arithmetic. This answer uses second order arithmetic. It's a theorem that it is impossible to define $\mathbb{Z}$ in $(\mathbb{R},+,\cdot)$
As mentioned in the comments, division is easy: define $a/b$ to be the number $c$ such that $cb=a$. It's identifying integers that is hard. Notably, $\mathbb{Z}$ and $\mathbb{Z}[\pi]$ have pretty much the same arithmatic structure. However, you can identify $0$ as the only number that satisfies $$\varphi(x):=\forall a(ax=x)$$ and then you can identify $1$ as the only number that satisfies $$\varphi'(x)=\forall a(\varphi(a)\lor a=ax)$$
Given these two constants, we can then recursively define the integers by using the fact that they are generated by $1$ as a group under addition, a la the Peano Axioms.
For your bonus question, again the comments had the right idea.