Truth-functional operators like the negation can only be applied to claims, e.g. I can say that the claim $P$ is not true by saying $\neg P$.
Such operators do not apply to objects (terms, to be exact), e.g. I can;t take an object $a$, and then claim to say something meaningful when I say 'not $a$'.
A typical mistake beginners of logic make is to translate 'a is not b' with $a = \neg b$, and again, this is a mistake since the negation is in front of an object, not a claim. The right translation should be $\neg a = b$.
You are making a similar mistake when you say $\neg Intersection(s,t)$, since $Intersection(s,t)$ is not a claim, but a term: it is the object that results from intersecting $s$ and $t$.