Let $u$ harmonic in $\Omega $ and $B(x,r)\subset \subset \Omega $. Then, $\partial _iu$ also harmonic, and thus by mean value property, $$\partial _iu=\frac{1}{|B(x,r)|}\int_{B(x,r)}\partial _iu\mathrm d y.$$ Using divergence theorem on $\partial _iu \boldsymbol e_i=div(u\boldsymbol e_i)$ (where $\boldsymbol e_i=(0,...,0,1,0,...,0)$ where the 1 is at the $i-$th position), we get
$$\partial _iu=\frac{1}{|B(x,r)|}\int_{\partial B(x,r)}u\nu_i,$$ where $\nu_i$ is the $i-$th component of the unit normal vector of $\partial B(x,r)$.
Then,
$$|\partial _iu|\leq \frac{1}{|B(x,r)|}\int_{\partial B(x,r)}|u\nu_i|.$$
Now, I don't understand how we get to $$|\partial _i u|\leq \frac{C}{r^{d}}r^{d-1}\|u\|_{L^1(B(x,4r)},$$ for a constant $C$.