Because of the continuity of the sample paths of Brownian motion, we have $$|B_{\sigma}| = \sqrt{2};$$ hence $B_{\sigma}^2=2$ which implies
$$\mathbb{E}(\sigma B_{\sigma}^2) = 2 \mathbb{E}(\sigma).$$
This means that everything boils down to calculating $\mathbb{E}(\sigma)$. To this end, recall that $M_t := B_t^2-t$ is a martingale. By the optional stopping theorem, $M_{t \wedge \sigma}$, $t \geq 0$, is a martingale. In particular,
$$\mathbb{E}(M_{t \wedge \sigma}) = \mathbb{E}(M_0)=0,$$
i.e.
$$\mathbb{E}(B_{t \wedge \sigma}^2) = \mathbb{E}(\sigma \wedge t). \tag{1}$$
Since $|B_{t \wedge \sigma}| \leq \sqrt{2}$ for all $t \geq 0$, we can apply the dominated convergence theorem to conclude that
$$2 = \mathbb{E}(B_{\sigma}^2) = \lim_{t \to \infty} \mathbb{E}(B_{t \wedge \sigma}^2).$$
On the other hand, the monotone convergence theorem yields
$$\mathbb{E}(\sigma) = \lim_{t \to \infty} \mathbb{E}(\sigma \wedge t).$$
Letting $t \to \infty$ in $(1)$, we find
$$\mathbb{E}(\sigma)=2.$$
Hence, $$\mathbb{E}(\sigma B_{\sigma}^2) = 4.$$