Okay. Let's beat this horse to death and then beat it some more.
We know: $e^{2k\pi i} = 1$ and $e^{(2k + 1)\pi i} = -1$ and therefore we know $e^{M + 2k\pi i} = e^{M}e^{2k\pi i} = e^{M}$ and $e^{M + (2k + 1)\pi i} =e^{M}e^{(2k+1)\pi i} = -e^{M}$.
So when we write something like $z = re^{\theta i}$ we also know that $z = re^{\theta i + 2k\pi i}$. But we don't have to write that as it is understood.
When we rise complex numbers to integer powers we have $z^n = (re^{\theta i})^n = (re^{\theta i + 2k\pi i})^n$ or $z^n = r^ne^{n\theta i} = r^ne^{n\theta i + 2(kn)\pi i}$. But as $2(kn)$ is also an even integer we don't have to write that as it is understood.
(This shouldn't surprise us. If $x = a$ then $x^n$ will only have one value.)
But when we raise things to a fractional power things do matter and we get multiple results. (Which shouldn't surprise us. If $x = a^n$ then $a = $ one of the $n$ $n$th roots of $x$.) If $z = re^{\theta i} = re^{\theta i + 2k\pi i}$ then $z^{1/n} = r^{\frac 1n} e^{\frac{\theta}ni + \frac{2k}n \pi i} = [r^{\frac 1n} e^{\frac{\theta}ni}]*e^{\frac{2k}n \pi i}$.
Now $0< \frac {2}n\pi < \frac {4}n\pi < .... < \frac {2(n-1)}n\pi$ or distinct non equal values for $k = 0..... n-1$ but for $k \ge n$ we have $\frac {2k}n \pi = \frac {2(k-n)}n\pi + 2\pi$ is not distinct, we have precisely $n$ distinct values of $n$th roots of $z$.
It's worth noting if $n= 2$ we have $z^{1/2} = \sqrt{r}e^{\frac{\theta} 2i + \pi i} = \{\sqrt{r}e^{\frac{\theta} 2i}, \sqrt{r}e^{\frac{\theta} 2i+ \pi i}\} = \{\sqrt{r}e^{\theta i/2 }, - \sqrt{r}e^{\theta i/2 }\} = \pm \sqrt{r}e^{\theta i/2}= \pm \sqrt{z} $. Which is our old familiar rule: $a^2 =z \implies a = \pm \sqrt{z}$.
In fact we can extend that: if $a^n = z = re^{\theta i}$ and we define $\sqrt[n]{z} = \sqrt[n]{r}e^{\theta i/n}$ then $a = \sqrt[n]{z}*\omega$ where $\omega = e^{\frac{2k}n \pi i}; k=0....(n-1)$. And we can further note that the $n$ distinct $\omega$s are the $n$ distinct $n$-th roots of $1$.
So now we've kill the horse. Let's keep beating it....
Take your problem:
$z^2 = ({2e^{i{\frac{\pi}{3}}}})^8$
we can do what you attempted and it will work:
$z = \pm({2e^{i{\frac{\pi}{3}}}})^4=$
$z = \pm 16e^{i\frac{4\pi}{3}}= \pm 8 \pm 8\sqrt{3}i $
or we could do it the thourough way:
$z^2 = (2e^{i\frac{\pi}{3}+ i 2k\pi})^8 = 2^8e^{i\frac{8\pi}3 + i16k\pi}$
$z = \pm2^4e^{i\frac{4\pi}3 + i8\pi} = \pm16e^{i\frac{4\pi}3}=\pm 8 \pm 8\sqrt{3}i$.