Let $u(x,t)=X(x)T(t)$ ,
Then $X(x)T'(t)=kX''(x)T(t)$
$\dfrac{T'(t)}{kT(t)}=\dfrac{X''(x)}{X(x)}=-s^2$
$\begin{cases}\dfrac{T'(t)}{T(t)}=-ks^2\\X''(x)+s^2X(x)=0\end{cases}$
$\begin{cases}T(t)=c_3(s)e^{-kts^2}\\X(x)=\begin{cases}c_1(s)\sin xs+c_2(s)\cos xs&\text{when}~s\neq0\\c_1x+c_2&\text{when}~s=0\end{cases}\end{cases}$
$\therefore u(x,t)=\int_0^\infty C_1(s)e^{-kts^2}\sin xs~ds+\int_0^\infty C_2(s)e^{-kts^2}\cos xs~ds$
$u(0,t)=u_0$ :
$\int_0^\infty C_2(s)e^{-kts^2}~ds=u_0$
$C_2(s)=u_0\delta(s)$
$\therefore u(x,t)=\int_0^\infty C_1(s)e^{-kts^2}\sin xs~ds+\int_0^\infty u_0\delta(s)e^{-kts^2}\cos xs~ds=\int_0^\infty C_1(s)e^{-kts^2}\sin xs~ds+u_0$
$u(x,0)=0$ :
$\int_0^\infty C_1(s)\sin xs~ds+u_0=0$
$\mathcal{F}_{s,s\to x}\{C_1(s)\}=-u_0$
$C_1(s)=\mathcal{F}^{-1}_{s,x\to s}\{-u_0\}=-\dfrac{2u_0}{\pi s}$
$\therefore u(x,t)=u_0-\dfrac{2u_0}{\pi}\int_0^\infty\dfrac{e^{-kts^2}\sin xs}{s}~ds=u_0~\text{erfc}\left(\dfrac{x}{2\sqrt{kt}}\right)$